Abstract

Twenty eight specimens of pyromorphite from the oxidised zone of the Broken Hill orebody, New South Wales have been analysed using EPMA methods. Material was selected to represent all of the varieties of pyromorphite which have been described by earlier workers as occurring in the deposit. Aside from minor Ca2+ substitution for Pb2+ and occasionally VO43- for PO43-, all specimens examined proved to be either pure end-member pyromorphite or arsenian pyromorphite with a maximum arsenate content corresponding to pyr2.1mim0.9. In one specimen phosphate-arsenate zoning is evident; minor vanadate is present in the more arsenian material. Calcium-lead zoning has been detected in a pale grey-coloured specimen. These zoning patterns indicate chemical variations in aqueous solution during crystal growth. The arsenate contents appear to be directly related to the original distribution of the primary arsenides and arsenic-bearing sulfosalts. The compositions have been related to those of the solutions from which they crystallised. Apatite is a major accessory in the primary ore and this would provide the requisite phosphate ions.

 
Download Complete Work

Bibliographic Data

Short Form
Inegbenebor et al., 1992, Rec. Aust. Mus., Suppl. 15: 29–37
Author
A. I. Inegbenebor; P. A. Williams; R. E. Bevins; M. P. Lambert; Alan D. Hart
Year
1992
Title
Composition of pyromorphites from Broken Hill, New South Wales
Serial Title
Records of the Australian Museum, Supplement
Volume
15
Start Page
29
End Page
37
DOI
10.3853/j.0812-7387.15.1992.81
Language
English
Date Published
16 October 1992
Cover Date
16 October 1992
ISBN
ISBN 0-7305-9990-6
ISSN
0812-7387
CODEN
RAMSEZ
Publisher
The Australian Museum
Place Published
Sydney, Australia
Subjects
GEOLOGY; MINERALOGY
Digitized
28 July 2009
Reference Number
81
EndNote
/Uploads/Journals/17762/81.enw
Title Page
/Uploads/Journals/17762/81.pdf
File size: 79kB
Complete Work
/Uploads/Journals/17762/81_complete.pdf
File size: 1410kB